Ultracold environment offers a first look at a chemical reaction

Friday, December 20, 2019 - 16:30 in Physics & Chemistry

Call it a serendipity dividend. A big one. Kang-Kuen Ni set out to do something that had never been done before. The Morris Kahn Associate Professor of Chemistry and Chemical Biology and of Physics and a pioneer of ultracold chemistry had built a new apparatus that could achieve the lowest temperature chemical reactions of any currently available technology. Then she and her team successfully forced two ultracold molecules to meet and react, breaking and forming the coldest bonds in the history of molecular couplings. While they were doing that, something totally unanticipated and important also happened. In such intense cold — 500 nanokelvin, or just a few millionths of a degree above absolute zero — the molecules slowed to such sluggish speeds that Ni and her team saw something no one has ever seen before: the moment when two molecules meet to form two new molecules. In essence, they captured a chemical reaction...

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