New thermodynamic model predicts plutonium solubility with iron

Thursday, August 4, 2011 - 10:31 in Earth & Climate

A hard-to-detect but stable form of iron helps convert subsurface plutonium from barely to very soluble, according to scientists at Pacific Northwest National Laboratory and Rai Enviro-Chem, LLC. Plutonium resides underground at weapons sites around the world. In one form, abbreviated Pu(IV), it essentially stays put. But when soluble iron and a stable iron are present the plutonium becomes soluble, easily mixing with water. Soluble plutonium is a concern because it could mix with groundwater and flow into rivers and streams.

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