A nano-sized sponge made of electrons

Tuesday, November 12, 2013 - 13:00 in Physics & Chemistry

A new chapter has been opened in our understanding of the chemical activity of nanoparticles says a team of international scientists. Using the X-ray beams of the European Synchrotron ESRF they showed that the electrons absorbed and released by cerium dioxide nanoparticles during chemical reactions behave in a completely different way than previously thought: the electrons are not bound to individual atoms but, like a cloud, distribute themselves over the whole nanoparticle. Inspired by the similarity of its shape, the scientists call this spatial distribution of particles an "electron sponge". The results were published on 12 November in the journal ACS Nano.

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