Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes

Tuesday, November 27, 2018 - 09:52 in Physics & Chemistry

Oxygen is an abundant element that can form undesired impurities or ceramic phases in metallic materials, while doping the element on metal can render substrates brittle. During interactions with metallic alloys, oxygen takes a state between oxide particles and frequently occurring random interstitials to form ordered oxygen complexes. In a new study, materials scientists Zhinfeng Lei and co-workers observed that unlike in traditional interstitial strengthening, such ordered interstitial complexes could form high-entropy alloys (HEAs) with unprecedented enhancement in strength and ductility in compositionally complex solid solutions. When the scientists doped a model TiZrHfNb HEA with 2.0 atomic percent (2 at%) oxygen, they observed substantially enhanced tensile strength and ductility, breaking a longstanding conflict on strength and ductility trade-off.

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