Silicon can be made to melt in reverse

Monday, August 2, 2010 - 03:28 in Physics & Chemistry

Like an ice cube on a warm day, most materials melt — that is, change from a solid to a liquid state — as they get warmer. But a few oddball materials do the reverse: They melt as they get cooler. Now a team of researchers at MIT has found that silicon, the most widely used material for computer chips and solar cells, can exhibit this strange property of “retrograde melting” when it contains high concentrations of certain metals dissolved in it.The material, a compound of silicon, copper, nickel and iron, “melts” (actually turning from a solid to a slush-like mix of solid and liquid material) as it cools below 900 degrees Celsius, whereas silicon ordinarily melts at 1414 degrees C. The much lower temperatures make it possible to observe the behavior of the material during melting, based on specialized X-ray fluorescence microprobe technology using a synchrotron — a type...

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